Catalytic platinum-initiated cation-olefin reactions with alkene terminating groups.
نویسندگان
چکیده
A series of phosphine-Pt(2+)-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral P2Pt(+2) catalyst provides up to 79% ee.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 44 شماره
صفحات -
تاریخ انتشار 2013